Research Article
Comparative study of two Nitroimidazopyridinehydrazone derivatives inhibition action for aluminium corrosion in 2M HCl: experimental and theoretical insights
Mougo André Tigori1*, Kouassi Francesco Adingra2, Aboudramane Koné1, Cissé M’Bouillé1,
Drissa Sissouma2, Paulin Marius Niamien2
1 Laboratoire des Sciences et Technologies de l’Environnement, UFR Environnement, Université Jean Lorougnon Guédé,
BP 150 Daloa, Côte d’Ivoire
2 Laboratoire de Constitution et de Réaction de la Matière, UFR SSMT, Université Félix Houphouët-Boigny,
22 BP 582 Abidjan 22, Côte d’Ivoire
Keywords: Aluminum, corrosion inhibitors, Mass loss techniques, Density Functional Theory, Quantitative Structure-Property Relationship
DOI:10.37273/chesci.cs205502631 • PDF
Abstract
The aim of this work is to study the inhibition performance of 2-benzylidene-1-(3-nitro H-imidazo[1,2-a]pyridin-2-yl)hydrazine (BNIH) and 2-(2-nitrobenzylidene)-1-(3-nitro H-imidazo[1,2-a]pyridin-2-yl)hydrazine (NBIH) for aluminum corrosion in 2M HCl. This study was carried out using experimental methods and theoretical calculations. Mass loss techniques indicate that BNIH has a greater inhibition effect than NBIH, with inhibition efficiencies of 95.78% and 91.56% respectively at 298K and 0.8mM concentration. Adsorption of these compounds on aluminum surface follows Villamil model. This adsorption occurs in two ways: physisorption and chemisorption. Theoretical results obtained from Density Functional Theory (DFT)/B3LYP-6-31G(d,p) and Quantitative Structure-Property Relationship(QSPR) helped to explain the interactions between each inhibitor and aluminum. These interactions justify the results obtained experimentally. Furthermore, this work reported the NO2 substituent effect in an organic compound.
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